Characterisation of Soot Emitted by Domestic Heating,Aircraft and Cars Using Diesel or Biodiesel   总被引：1，自引：0，他引：1  

Anne?Smekens  Ricardo?Henrique?Moreton?Godoi  Patrick?Berghmans  René?Van?GriekenEmail author 《Journal of Atmospheric Chemistry》2005,52(1):45-62

The characterisation of aggregates, like soot, firstly requires the determination of the size distribution of the primary particles. The primary particle size of combustion generated aggregates depends upon the combustion environment and the formation conditions, such as temperature, pressure and fuel-to-air ratio, among others. Since the combustion characteristics are different in the different types of burners, the characterisation of primary particles may offer the possibility to distinguish soot from different sources. In this paper, we present the signature of the primary particles and the aggregates of soot emitted by cars using diesel or biodiesel, by domestic heating, and by aircraft exhausts, which can be considered as the major sources as derived from measurements on transmission electron micrographs. The size distributions of all aggregates types with different aerodynamic diameter were log-normal and quasi-monodisperse. The size distribution of the primary particles for soot emitted by different sources showed minor differences. However, a comparison between the diameter of the primary particles and those obtained using a standard method for carbon black revealed discrepancies. The median diameter of the primary particles was combined with the median number of primary particles in an aggregate to calculate the relative particle surface area available for adsorption. In a similar way, the relative specific surface area was determined. The surface area was measured using the Brunauer-Emmett-Teller (B.E.T.) nitrogen adsorption method and the relative surface area available for adsorption was calculated.  相似文献   

Embryotoxicity of the antifouling biocide zinc pyrithione to sea urchin (Paracentrotus lividus) and mussel (Mytilus edulis)     

Bellas J  Granmo K  Beiras R 《Marine pollution bulletin》2005,50(11):1382-1385

The effects of the new antifouling compound zinc pyrithione (Zpt) on the embryonic development of sea urchin (Paracentrotus lividus) and mussel (Mytilus edulis) were investigated in laboratory toxicity tests. The median effective concentrations (EC50) were 7.7 nM for sea urchin embryos and 8 nM for mussel embryos. Toxic effects of Zpt on the larval growth of the sea urchin were detected at 0.5 nM. Predicted environmental concentrations of Zpt in pleasure craft harbours are higher than the predicted no effect concentrations for sea urchin and mussel embryos, indicating that Zpt may pose a threat to those species from exposure in the field.  相似文献   

Singularity and Nonnormality in the Classification of Compositional Data     

Geoffrey C. Bohling  John C. Davis  Ricardo A. Olea  Jan Harff 《Mathematical Geology》1998,30(1):5-20

Geologists may want to classify compositional data and express the classification as a map. Regionalized classification is a tool that can be used for this purpose, but it incorporates discriminant analysis, which requires the computation and inversion of a covariance matrix. Covariance matrices of compositional data always will be singular (noninvertible) because of the unit-sum constraint. Fortunately, discriminant analyses can be calculated using a pseudo-inverse of the singular covariance matrix; this is done automatically by some statistical packages such as SAS. Granulometric data from the Darss Sill region of the Baltic Sea is used to explore how the pseudo-inversion procedure influences discriminant analysis results, comparing the algorithm used by SAS to the more conventional Moore–Penrose algorithm. Logratio transforms have been recommended to overcome problems associated with analysis of compositional data, including singularity. A regionalized classification of the Darss Sill data after logratio transformation is different only slightly from one based on raw granulometric data, suggesting that closure problems do not influence severely regionalized classification of compositional data.  相似文献   

Some peculiarities in the Asteroidal Belt     

Cordeiro  Ricardo R.  Quiroga  Ramon J. 《Earth, Moon, and Planets》1986,34(2):117-132

The analysis of the fine structure of the Asteroidal Belt evidenciates a group of asteroids next to the resonance 4/9 with Jupiter. In this group and in other groups associated to the Hirayama families there are indications that their orbital parameters can be represented by quantum numbers as defined here and in two of our previous works. Together with this the distribution of the eccentricities and inclinations of the orbital planes of short period comets and diverse type of asteroids indicates that they can be classified as objects with e > sin i and objects with e > sin i with a limit e = sin i which determinates geometrical properties of the orbits related with discrete states in the solar system. This study lets open the possibility of following studies in order to confirm the quantum characteristics of the Asteroidal Belt being these characteristics common to all the solar system and depending of the same fundamental constant of action per mass unit H ₀ = 1/2 ₀ × T ₀ (potential × time) because only a small part of all the available data in the Asteroid Belt is used here.  相似文献   

Quantifying Multipath Using MNR Ratios     

Ricardo Ernesto Schaal  Nicola Paciléo Netto 《GPS Solutions》2000,3(3):44-48

The global positioning system (GPS) is used increasingly to control horizontal and vertical displacement of large civil constructions. The displacements can occur over varius time scales. For example, in case of the loading test of a bridge, the time span between measurements is on the order of 30 min. The achievable precision in the vertical component and its relation to residual multiplath effects become critically important in such aaplications. A multipath-to-noise ratio (MNR) on individual satellites is introduced to quantify the multipath effects. ? 2000 John Wiley & Sons, Inc.  相似文献   

Tectonic significance of an earthquake sequence in the Zacoalco half-graben, Jalisco, Mexico     

Javier F. Pacheco  Carlos A. Mortera-Gutirrez  Hugo Delgado  Shri K. Singh  Raúl W. Valenzuela  Nicolai M. Shapiro  Miguel A. Santoyo  Alejandro Hurtado  Ricardo Barrn  Esteban Gutirrez-Moguel 《Journal of South American Earth Sciences》1999,12(6):55

We studied a sequence of small earthquakes that occurred during the months of April and May of 1997, in Jalisco, southwestern Mexico. The earthquakes were located along a set of active faults that form the Zacoalco half-graben (La Lima fault system), west of Lake Chapala, within the rift–rift–rift triple junction. A total of 33 events were located, with magnitudes ranging from 1.5 to 3.5, recorded by a portable array of broadband seismographs. We identified two groups of events: one corresponding to a shallow normal fault, synthetic to La Lima fault system, and another group associated with a deeper fault. The events that occurred on the synthetic fault show normal faulting oriented on a NW–SE plane, dipping shallowly towards the SW. The other group of mechanisms showed either a normal fault oriented NW–SE and dipping steeply to the NE, or a very shallow-dipping normal fault, dipping to the SW. Earthquake distribution and fault plane solutions suggest that the Zacoalco half-graben developed from blocks that rotate as slip occurs on listric faults. These mechanisms could represent the type of motion expected for larger earthquakes in the area, like the one that occurred in 1568.  相似文献   

Tectonic implications of the earthquake swarm of 1997 in the Michoacan Triangle, Mexico     

Javier F. Pacheco  Carlos Valds-Gonzlez  Hugo Delgado  Shri K. Singh  F. Ramn Zuiga  Carlos A. Mortera-Gutirrez  Miguel A. Santoyo  Jaime Domínguez  Ricardo Barrn 《Journal of South American Earth Sciences》1999,12(6):73

An earthquake swarm occurred during February and March 1997 in the vicinity of the Tancitaro Volcano, in the southern part of the tectonically complex Michoacan Triangle. A study of these events provides an opportunity to map the active faults in the area and to learn if the orientation and the sense of motion on these faults are consistent with the mapped faults and the alignment of cinder cones in the region. The foci of 230 earthquakes, which could be located, are distributed between 10 and 18 km depth, and show an alignment in, roughly, a NE direction. The focal mechanisms and seismic moments of the 27 best-recorded events were determined by waveform modeling of P and S waves. These mechanisms show two distinct patterns. More than 50% of the solutions are left-lateral strike–slip mechanisms with a normal component. The preferred fault plane strikes NE. Another group of events, probably caused by triggered seismicity on the Chapala–Oaxaca fault zone, shows left-lateral strike–slip mechanisms with a large-thrust component on NW-trending faults. S wave splitting shows 1–2.5% crustal-anisotropy. The direction of the anisotropy coincides with the NE alignment of events, and the preferred nodal plane. This is also the alignment of cinder cones, suggesting that preexisting fractures and cracks are responsible for the seismicity and anisotropic behavior of the crust. The resulting stress orientation, NE compression, is the one expected for the fore-arc region. We conclude that although Michoacan Triangle lies in the Trans-Mexican Volcanic Belt, it does not form part of this stress province where the stress orientation is NS extension.  相似文献   

Multispectral remote sensing of biomass burning in West Africa     

J. Ricardo  A. De França  J. -M. Brustet  J. Fontan 《Journal of Atmospheric Chemistry》1995,22(1-2):81-110

Remote sensing measurements provide a vauable means of determining the extent of burning areas and of estimating the overall distribution of pollutant sources (identified from experimental studies) in time and space. This distribution has to be taken into account in the boundary conditions of chemistry atmospheric models.Recent methods developed for the remote sensing of active fires in tropical or temperated forest zones, have been found to be completely inadequate for fire detection on West African savannas. In order to accurately estimate the active fire distribution in the function of different sorts of West African savannas (Sahelian, Sudanian and Guinean) and forests, a multispectral methodology has been developed based on NOAA/11-AVHRR satellite data, with the purpose of eliminating as much as possible the problems related to large surface heterogeneity, confusion and bias, produced by clouds, smoke, haze, background emissivities, etc.Unlike other methods, the results show that the multispectral method, in spite of its selectivity, provides realistic results, and does not under- or over-estimate the number of fires that can be sensed by the satellite. Consequently, this methodology is more appropriate than the simplest ones for a systematic sensing of this phenomenon.  相似文献   

U–Pb evidence for a polyorogenic evolution of the HP–HT units of the NW Iberian Massif     

Javier Fernández-Suárez  Fernando Corfu  Ricardo Arenas  Alberto Marcos  José R. Martínez Catalán  Florentino García  Jacobo Abati  Francisco J. Fernández 《Contributions to Mineralogy and Petrology》2002,143(2):236-253

. A isotope dilution thermal ionisation mass spectrometry U-Pb geochronological study was carried out on the high-pressure and high-temperature units (HP-HT units) overlying the oceanic suture in the Allochthonous Complexes of the NW Iberian Variscan Belt. The rocks investigated are seven granulite- to eclogite-facies paragneisses and one leucosome within mafic high-pressure granulites in the Ordenes and Cabo Ortegal Complexes of NW Spain. U-Pb dating of zircon, monazite, titanite and rutile reveal the presence of a pervasive Early Ordovician metamorphic event at ca. 500-480 Ma and a later Early Devonian event at ca. 400-380 Ma. The U-Pb ages, in conjunction with petrological and structural data, indicate that the high-pressure event recorded by these rocks is Early Ordovician in age. Monazite ages in the paragneisses suggest that peak metamorphic conditions were reached at ca. 500-485 Ma. Subsequently, the rock ensemble underwent exhumation accompanied by partial melting and zircon growth at ca. 485-470 Ma. Melting of mafic granulites was coeval with this latter episode as indicated by zircon crystallisation age in the leucosomes dated at ca. 486 Ma. Based on these data and on the general features of magmatism and metamorphic evolution, it is proposed that this process took place at a convergent plate boundary within a peri-Gondwanan oceanic domain. Monazite, titanite and rutile data in some of the samples studied show evidence of a second metamorphic episode that took place between ca. 400 and 380 Ma (with a peak at ca. 390-385 Ma). This Early Devonian event, at variance with the previous one, was not pervasive, but, rather, was localised in areas of intense Variscan tectonothermal reworking. It is claimed that this later metamorphic event was recorded by the U-Pb system in areas where monazite and titanite growth was enhanced by fluid circulation in highly strained rocks (Variscan shear zones). According to previous structural studies and Ar-Ar dating of fabrics, this Early Devonian episode took place as the HP-HT units were deformed and thrusted upon the ophiolitic units in the early stages of the Variscan collision.  相似文献   

Looting, collecting, and the destruction of archaeological resources     

Ricardo J. Elia 《Natural Resources Research》1997,6(2):85-98

Archaeological sites, the material remnants of our human past, are finite and nonrenewable cultural resources that are under constant threat from environmental forces, development activities, warfare, vandalism, and looting. Site looting is the destructive removal of archaeological objects to supply the art market. Looting is part of an economic system, the antiquities market, that works to supply the demand of collectors for archaeological objects. The destruction of archaeological resources by looters is an international crisis and threatens to obliterate the world’s cultural heritage and our ability to understand past cultures. The scale and intensity of the looting problem can be estimated by studying the extent of site destruction in countries of origin and by investigating the sources of antiquities held by collectors. Finding a solution to the problem of looting will require a focus on the demand side of the market (i.e., collectors) instead of the traditional focus on the supply side (looters, dealers)  相似文献